There's a difference between proof and good evidence. I would sincerely hope that you at least have good evidence before making important decisions in other areas. And for your wife, I'm sure there is plenty of evidence that she loves you. No one is asking for 100% proof of anything, science doesn't work like that.
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Please visit my website here! It's got lots of information about atheism/theism and support for new atheists.
Index of useful threads and discussions
Index of my best videos
Quickstart guide to the forum