Possibly; the Mock The Week bit sounds about right but I'm not connecting it with Russell Howard. I'll have to dig out the "Too Hot For TV" DVDs when I get home, or see what YouTube's got.
At the age of five, Skagra decided emphatically that God did not exist. This revelation tends to make most people in the universe who have it react in one of two ways - with relief or with despair. Only Skagra responded to it by thinking, 'Wait a second. That means there's a situation vacant.'